男,1989年出生,德州学院生物物理研究院副教授。2008年至2012年就读于曲阜师范大学杏坛学院应用化学专业,获理学学士学位。2012年至2015年就读于曲阜师范大学无机化学专业,获理学硕士学位。2015年至2020年就读于吉林大学物理化学专业,获理学博士学位。2020年至今德州学院讲师、副教授。
研究方向:
1. 金属催化有机合成反应的理论模拟
2. 电化学催化绿色有机合成机器小分子活化的理论模拟与设计
3. 碳化硅材料析氢催化剂设计
研究成果:
1. 研究兴趣为利用理论方法阐释过渡金属催化和无金属(催化)有机反应机理,揭示影响化学反应速率和选择性的因素及其作用机制,探索反应优化和新反应开发的理论依据。
2. 电催化绿色有机合成理论模拟,揭示了双PCET机制介导的查尔酮、硫代缩醛和色酮类底物的氢吡啶化反应,此外,利用双PCET介导的活化机制,实现了一系列惰性N-杂环化合物的吡啶化反应的设计。
科研项目:
1. 山东省自然科学基金 (ZR2021QB159) 主持 第一位 2022.01-2024.12
论文发表:
2022:
1. Cong Niu, Jianjing Yang, Kelu Yan, Jiafang Xie, Wei Jiang, Bingwen Li, and Jiangwei Wen* Electrochemical ammonium-cation-assisted pyridylation of inert N-heterocycles via dual-proton-coupled electron transfer. iScience 25, 104253, May 20, 2022.
2. Jianjing Yang, Jing Ma, Kelu Yan, Laijin Tian, Bingwen Li,* and Jiangwei Wen,* Electrochemical Ammonium Cation-Assisted Hydropyridylation of Ketone-Activated Alkenes: Experimental and Computational Mechanistic Studies. Adv. Synth. Catal. 2022, 364, 845–854
3. Xue-Mei Chen, Bing-Wen Li, Mei-Yan Wang*, Jing-Yao Liu,* Theoretical study on the mechanism of Ni−Al bimetallic catalyzed dual C−H cyclization of amides and alkynes. Molecular Catalysis 522 (2022) 112230
2021:
4. Bing-wen Li, Mei-yan Wang*, Jing-yao Liu,* DFT study on the mechanism of palladium(0)-catalyzed reaction of o-iodoanilines, CO2, and CO. Molecular Catalysis 501 (2021) 111344
5. Hong-Yan Lu *, Na Jiao , Bing-Wen Li, Wen-Cai Yi,*, Ping Zhang,* Hydrogenated group IV-V monolayer HAB6: A new type of Dirac material constructed by isoelectronic rule. Applied Surface Science 554 (2021) 149635
2020:
6. Mei-yan Wang, Li Chen, Bing-wen Li and Jing-yao Liu* DFT study on the mechanism of bimetallic Pd–Zncatalyzed cycloaddition of alkynyl aryl ethers with internal alkynes Dalton Trans., 2020, 49,2914
7. Bing-Wen Li, Mei-Yan Wang*, Jing-Yao Liu* DFT study on the mechanism of palladium(II)-catalyzed reaction of allylsubstituted 3,4-dienoate, alkyne and carbon monoxide. Molecular Catalysis 492 (2020) 111028
8. Xinli Liu, Bingwen Li, Xiufang Hua, and Dongmei Cui* 1,2-Hydroboration of Pyridines by Organomagnesium Org. Lett. 2020, 22, 4960−4965
2013-2019 (Master-Ph.D.):
9. Bing-wen Li, Mei-yan Wang,* Sheng Fang, and Jing-yao Liu* DFT Study on the Mechanism of Palladium(0)-Catalyzed Reaction of Aryl Iodides, Norbornene, and Di-tert-butyldiaziridinone Organometallics 2019, 38, 2189−2198
10. Sheng Fang, Meiyan Wang, * Jingjing Liu, Bingwen Li and Jing-yao Liu * Theoretical study on the reaction mechanism of “ligandless” Ni-catalyzed hydrodesulfurization of aryl sulfide RSC Adv., 2017, 7, 51475–51484
11. Weirong Wu, Siwei Bi,* Yuxia Liu, Yanan Tang and Bingwen Li Insight into Pd-catalyzed branching cyclizations of enediyne-imides towards furo[2,3-b]pyridines: a DFT study Org. Biomol. Chem., 2015, 13, 11539–11549
12. Bingwen Li, Siwei Bi,*, Yuxia Liu, Baoping Ling, and Ping Li. Role of Acetate and Water in the Water-Assisted Pd(OAc)2‑Catalyzed Cross-Coupling of Alkenes with N‑Tosyl Hydrazones: A DFT Study. Organometallics 2014, 33, 3453−3463
招生启事:
理论模拟方面:
1. 欢迎有志于从事化学科学研究的本科生(物理、化学)到实验室做科研训练。
实验合成方面:
2. 欢迎勤奋、踏实、上进的同学报考有机化学方向硕士研究生(合作导师:曲阜师范大学化学与化工学院 文江伟副教授)
联系方式:libingwen@dzu.edu.cn and wenjy@qfnu.edu.cn